0000007425 00000 n Serious Eye Damage/Eye Irritation Category 1. Company. 0000004083 00000 n 0000008433 00000 n If applicable, use process enclosures, local exhaust ventilation, or other engineering controls Beilstein/REAXYS Number 3587154 . Revised on 04/21/2016 Page 1 of 6 Safety Data Sheet Ammonium Hydroxide 3N 1. For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam extinguishers. Ammonium hydroxide is highly toxic whether it is inhaled, ingested, or absorbed through the skin. P270 - Do not eat, drink or smoke when using this product. <> Direct contact with the eyes can cause blindness if not washed away immediately within the first 10 seconds. Fisher Scientific. 2.4. startxref Other Hazards Ammonium hydroxide is very volatile and may release ammonia as a gas. Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). When employees work with industrial chemicals, they often are not using products they will find at home. Print Share on: Evidence. Possibility of Hazardous Reactions Ammonium hydroxide will react exothermically with acids. Workers in all industries should know that, despite its common usage, ammonia poses health risks and hazards that require proper use of personal protective equipment (PPE) and safe use and handling procedures. May adversely affect pH of aquatic ecosystems. 0000001303 00000 n Used in everything from household cleaners to industrial processes, it is toxic in all solutions. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. {�k��Ο�(���(�?�s_���/C�V��0�ਇm�l8a���;�����•|�1�3m����3~N�֙���y����4�?�4�[��JEL�. << Product: Ammonium Hydroxide Revision Date: 12/03/2012 4/7 Engineering Controls: Ensure adequate ventilation. 0000018893 00000 n HAZARDS IDENTIFICATION Terra Industries Inc. Terra Centre – 600 Fourth Street Sioux City, Iowa … Conditions to Avoid Avoid ammonium hydroxide contact with chlorine, which forms a chloramine gas, which is a primary skin irritant and sensitizer. 0000018685 00000 n 0000003112 00000 n endobj endstream endobj 29 0 obj <. *Please select more than one item to compare 0000001439 00000 n 0000013231 00000 n 0000019272 00000 n 0000000016 00000 n %���� Ammonia gas is generally not considered a serious fire or explosion hazard because ammonia/air mixtures are difficult However concentrated ammonia solutions may give off ammonia vapours. Ammonium hydroxide solution ACS reagent Synonym: Ammonia aqueous, Ammonia water CAS Number 1336-21-6. 0000005636 00000 n 0000004611 00000 n As the nation's health protection agency, CDC saves lives and protects people from health, safety, and security threats. PRODUCT AND COMPANY IDENTIFICATION Product name: Ammonium Hydroxide ~30% Product code: 05870-16 Supplier: StatLab Medical Products 2090 Commerce Drive McKinney, TX 75069 800-442-3573 972-436-1369 Fax statlab.com Synonym: None. Strong oxidizers, acids, halogens, salts of silver & zinc [Note: Corrosive to copper & galvanized surfaces.] xref 0000010276 00000 n On burning: release of toxic and corrosive gases/vapours (nitrous vapours). It is soluble in water. Molecular Weight 35.05 . 0 <<0E3A66ABCCE85E48B6E7192D2C7FA130>]>> However, ammonium hydroxide is one exception. Y>ákî'ÅI9‰bÀrR/OÕIÚϒ‡à÷+aoÁ¶’ßï? 0000006041 00000 n Although the name ammonium hydroxide suggests an alkali with composition [NH 4 +][OH −], it is actually impossible to isolate samples of NH 4 OH. %%EOF Unknown Acute Toxicity (GHS-US) No data available. 0000019076 00000 n Safety Data Sheet (SDS) SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Ammonium Hydroxide 1.1 M - 14.8 M Flinn Scientific, Inc. P.O. Ammonium hydroxide is a colorless liquid with a strong odor and bad taste. %PDF-1.6 %âãÏÓ §ðÔ¶ËÞTšz͑W®,£ùž¥Ö˜›‹%|$f‘F”ØßÌßznÅO§Cƒ¬!š¥ÿ£TehXãpýÁ©/yþô@=rÚ X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? 0000018450 00000 n P273 - Avoid release to the environment. Exposure Routes. inhalation, ingestion (solution), skin and/or eye contact (solution/liquid) Symptoms. 4 0 obj Skin Corrosion/irritation Category 1 B. 0 colorless liquid with a strong odor and bad taste, Four Steps to Conducting a Job Safety Analysis in the Canadian Workplace, Train over any hazardous chemicals that employees may be exposed to, Train employees to detect and respond … Level of Concern . Ammonia and Ammonium Hydroxide are used in a large variety of products including hair dyes, hair bleaching products, shaving cream and hair grooming products. Tetramethylammonium hydroxide (TMAH or TMAOH) is a quaternary ammonium salt with the molecular formula N(CH 3) 4 + OH −.It is commonly encountered as concentrated solutions in water or methanol.The solid and solutions are colorless, or yellowish if impure. 28 0 obj <> endobj The major hazards encountered in the use and handling of ammonium hydroxide stem from its toxicologic properties. Such a precipitate can explode on stirring [MCA Case History 1554 1968]. The gas is an eye, skin and respiratory irritant. Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. Tetramethylammonium hydroxide is a solid in the hydrated form or a colorless liquid with a strong ammonia -like odor. 0000002366 00000 n 61 0 obj <>stream Product:)Ammonium)Hydroxide,)50%)v/v) RevisionDate:)05/18/2016) 6/7) Ecotoxicological Data: Water: Not applicable. fExposure can irritate the eyes, nose and throat. 0000015924 00000 n Environmental Effects: Very toxic to aquatic life. When dissolved in water, Ammonia forms Ammonium Hydroxide (H5NO). May cause respiratory irritation. ... in this product - not the product itself - compared to other product formulations. It can be denoted by the symbols NH 3 (aq). P264 - Wash exposed skin thoroughly after handling. trailer 0000001926 00000 n 0000004305 00000 n The vapors are extremely irritating to the eyes. One Reagent Lane. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Take all appropriate precautions. Incompatibilities & Reactivities. 3 Effective date : 11.05.2014 Page 2 of 6 Ammonium Hydroxide, 3M Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Section 3: Composition / Information on Ingredients Ammonium Hydroxide, (1336-21-6), 1-2% as Ammonia Water: (CAS No. 0000006157 00000 n Evolves toxic gaseous ammonia with strong bases. Ammonium hydroxide is a caustic inorganic base (an alkaline substance). The following acute (short-term) health effects may occur immediately or shortly after exposure to Ammonium Hydroxide: fContact can severely irritate and burn the skin and eyes leading to eye damage. Although employees may use ammonium hydroxide both at home and at work, employers must ensure they are aware of the unique dangers of the chemical. Very toxic to aquatic life . Ammonia (H3N) is a gas. 0000001520 00000 n 0000003612 00000 n Fair Lawn, NJ 07410. PRODUCT AND COMPANY IDENTIFICATION Product Name: Ammonium Hydroxide 3N Synonyms/Generic Names: Aqueous Ammonia; Strong Ammonia Solution; Stronger Ammonia Water Product Number: 8133 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. It is corrosive to metals and tissue. Causes severe skin burns and eye damage. Compare Products: Select up to 4 products. Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Made in the United States of America Ammonia: LC50, Water Flea (Daphnia magna): 0.66 mg/L 48 h Persistence and Degradability: Expected to be readily biodegradable. fInhaling Ammonium Hydroxidecan irritate the lungs causing coughing and/or shortness of breath. Avoid ammonium hydroxide contact with chemicals such as mercury, chlorine, iodine, bromine, silver oxide or hypochlorites; they can form explosive compounds. Wear appropriate protective clothing to … : with (some) halogens compounds, with … decomposition products. %PDF-1.4 0000003840 00000 n Ammonia reacts with strong oxidizers, acids, halogens (including chlorine bleach), and salts of silver, zinc, copper, and other heavy metals. 0000003577 00000 n Ammonium hydroxide, ACS reagent, 28-30% solution in water, ACROS Organics™ CAS=1336-21 … >> 0000011267 00000 n For use on containers that store Ammonium Hydroxide to ensure the workplace is aware of the immediate chemical hazards that are present. AMMONIA SOLUTION, STRONG, AMMONIA WATER, AMMONIA, AQUEOUS SOLUTION, AMMONIUM HYDROXIDE, AMMONIUM HYDROXIDE ((NH4)(OH)), AQUA AMMONIUM, HARTSHORN SPIRIT, SPIRIT OF HARTSHORN, and STRONG AMMONIA SOLUTION ý„da BL:†nCò“é [Ö ×-|ëúÀ7LôÿDÄÛÚVíp)J0æs~t@û‘ãä˜ñVÖêg,0G'¹ ¬bÎm™Ë–õ•@ÅëæåºS› ª‚ÕÛò‹å0†(ĀxÁX,C­Ý ü¥F$°üšÿÛ /Producer(Sub Systems, Inc.)/CreationDate(D:20190425105311+04'00')/ModDate(D:20190425105311+04'00')/Creator(Sub Systems, Inc.) Reacts with aqueous silver nitrate sodium hydroxide to give a black precipitate of silver nitride. 0000002525 00000 n On heating: release of toxic/corrosive/combustible gases/vapour s (ammonia). 0000012304 00000 n MDL number MFCD00066650 "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#�޽���6����"������UH��8/�?CZ7�����D|z�?���W5M��78����k"^�8�ö����$���p(�?kӴ������ׅL�}��~�Gm�ֽ�{{���>~�O4��v���{���x��?�O�g�|���4k�j�uG�|����ig�I���f�i����7�������x����z�ίgu���}�=�h������FR��G�\:��X���ÔY�S�so/����m��{��^��n�g��������J�?�_����˝��l��R�� ~ ������!J�����s��A���'Y*��ߤ\=���f/�� ��3[��= ����'u~ͻ�/���g�����i���� �_C�|�2��S�A^�����|z��;���^���jy�h>~�� ��{�7? Concentrated solution violent to explosive reaction with many compounds e.g. Search results for 1336-21-6 at Sigma-Aldrich. AMMONIUM HYDROXIDE reacts exothermically with acids. Ammonia vapor, in concentrations of 16-25% volume by weight in air, is flammable, toxic by inhalation and corrosive. 7732-18-5), 98-99% Section 4: First Aid Measures Toxic by all routes (ie, inhalation, ingestion, and dermal contact), exposure to this colorless, intensely pungent-smelling liquid may occur from its use in fertilizers, dyes, explosives, plastics, cleansing agents, fibers, and resins. Ammonium hydroxide is not a flammable liquid; however, ammonia gas is flammable. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9402 Signal Word DANGER SECTION 2 — HAZARDS IDENTIFICATION Hazard class: Acute toxicity, oral (Category 4). Health issue . '’ü¸Š¥q P271 - Use only outdoors or in a well-ventilated area. stream 0000004534 00000 n 0000006391 00000 n 0000000976 00000 n Ventilation rates should be matched to conditions. As a result, ammonium hydroxide is a severe eye, skin, and respiratory tract irritant, and readily burns tissue with which it comes in contact. 0000001700 00000 n Linear Formula NH 4 OH . 28 34 Material uses: Laboratory Reagent. Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. Tel: (201) 796-7100. AMMONIUM HYDROXIDE can be found in 65 products. Ammonium Hydroxide / 1336-21-6 39.1% 25 ppm TWA Water / 7732-18-5 60.9% 35 ppm STEL 50 ppm PEL Contains 19% ammonia as NH3 300 ppm IDLH 3. SAFETY DATA SHEET: AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS A631.7A INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800 … 0000009368 00000 n Safety Data Sheet Ammonium Hydroxide Issue Date: 12/30/2015 V1.0 1. Source. RTECS:BQ9625000 - Ammonium hydroxide - The Registry of Toxic Effects of Chemical Substances | CDC/NIOSH 1 0 obj Ammonium hydroxide itself is non-combustible. Health Hazard Ammonium hydroxide solutions are alkaline solutions, meaning they have high pH level. It is also a highly corrosive chemical and a skin, eye, and respiratory irritant. Product Name: Ammonium Hydroxide (10% to 30%) Synonyms: Ammonium Hydroxide Solutions, Aqua Ammonia, Aqua Ammonia Solutions, Ammonia Solutions, Ammonia Aqueous, Ammonia Water CAS REGISTRY NO: 1336-21-6 Supplier: Tanner Industries, Inc. 735 Davisville Road, Third Floor Southampton, PA 18966 Website: www.tannerind.com Telephone (General): 215-322-1238 Ammonia vapors are released when heated. In everything from household cleaners to industrial processes, it is toxic in all solutions Issue Date 12/30/2015. H Persistence and Degradability: Expected to be readily biodegradable may release ammonia as a.. 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( GHS-US ) No Data available & galvanized surfaces. if not washed away immediately within the first 10.... Are difficult Incompatibilities & Reactivities [ MCA Case History 1554 1968 ] Hazardous Reactions Ammonium hydroxide react! Hydroxide is very volatile and may release ammonia as a gas Ingredients Ammonium 3N. Note: corrosive to copper & galvanized surfaces. water, ammonia gas is not. To be readily biodegradable with many compounds e.g compounds e.g, which forms a chloramine,... Ammonium Hydroxidecan irritate the lungs causing coughing and/or shortness of breath % volume weight... On heating: release of toxic and corrosive gases/vapours ( nitrous vapours ) only outdoors or in well-ventilated! [ MCA Case History 1554 1968 ] substance ) product formulations sodium hydroxide to give a black precipitate silver.